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Enhancement of High-Density Polyethylene Properties by Impregnation with Inorganic Alumina Filler

Received: 10 April 2017     Accepted: 11 April 2017     Published: 27 April 2017
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Abstract

The influence of filler size and content on the mechanical and rheological properties (thermal conductivity, impact strength, hardness and melt flow index (MFI) of Al2O3/high-density polyethylene (HDPE) composites have been studied. Concentration of alumina was varied up to 30% by weight. The composites were prepared using a two-roll mill and then test specimens were prepared by injection molding. Thermal conductivity, hardness, impact strength and melt flow rate of the composites increased with decreased particle sizes and increased particle content with exceptions at certain concentrations due to non-uniform distributions of particles and agglomerates formed by the particles. As an example, the best integrated thermal conductivity was shown by a 75 micron-Al2O3/HDPE composite at 15% wt. alumina content, while the 212 micron- Al2O3/HDPE composite at 20 wt.% alumina content. For the same alumina content of 15% concentration by weight out of the three particle sizes. 75, 212 and 850 microns, the 75 micron-Al2O3/HDPE composite gave the highest thermal conductivity, which was nearly 50% higher than that of pure HDPE. Enhancement in impact strength and Hardness Rockwell were up to 300% and 400% as compared to the pure HDPE respectively. The Al2O3 with small particle size is generally more efficient for the enhancement of the impact strength.

Published in American Journal of Chemical Engineering (Volume 5, Issue 3-1)

This article belongs to the Special Issue Oil Field Chemicals and Petrochemicals

DOI 10.11648/j.ajche.s.2017050301.16
Page(s) 49-54
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

HDPE, Thermal Conductivity, Impact Strength, Melt Flow Index, Hardness, Filler, Alumina

References
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Cite This Article
  • APA Style

    Koyejo Oduola, Fabian Ozioko. (2017). Enhancement of High-Density Polyethylene Properties by Impregnation with Inorganic Alumina Filler. American Journal of Chemical Engineering, 5(3-1), 49-54. https://doi.org/10.11648/j.ajche.s.2017050301.16

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    ACS Style

    Koyejo Oduola; Fabian Ozioko. Enhancement of High-Density Polyethylene Properties by Impregnation with Inorganic Alumina Filler. Am. J. Chem. Eng. 2017, 5(3-1), 49-54. doi: 10.11648/j.ajche.s.2017050301.16

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    AMA Style

    Koyejo Oduola, Fabian Ozioko. Enhancement of High-Density Polyethylene Properties by Impregnation with Inorganic Alumina Filler. Am J Chem Eng. 2017;5(3-1):49-54. doi: 10.11648/j.ajche.s.2017050301.16

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  • @article{10.11648/j.ajche.s.2017050301.16,
      author = {Koyejo Oduola and Fabian Ozioko},
      title = {Enhancement of High-Density Polyethylene Properties by Impregnation with Inorganic Alumina Filler},
      journal = {American Journal of Chemical Engineering},
      volume = {5},
      number = {3-1},
      pages = {49-54},
      doi = {10.11648/j.ajche.s.2017050301.16},
      url = {https://doi.org/10.11648/j.ajche.s.2017050301.16},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.s.2017050301.16},
      abstract = {The influence of filler size and content on the mechanical and rheological properties (thermal conductivity, impact strength, hardness and melt flow index (MFI) of Al2O3/high-density polyethylene (HDPE) composites have been studied. Concentration of alumina was varied up to 30% by weight. The composites were prepared using a two-roll mill and then test specimens were prepared by injection molding. Thermal conductivity, hardness, impact strength and melt flow rate of the composites increased with decreased particle sizes and increased particle content with exceptions at certain concentrations due to non-uniform distributions of particles and agglomerates formed by the particles. As an example, the best integrated thermal conductivity was shown by a 75 micron-Al2O3/HDPE composite at 15% wt. alumina content, while the 212 micron- Al2O3/HDPE composite at 20 wt.% alumina content. For the same alumina content of 15% concentration by weight out of the three particle sizes. 75, 212 and 850 microns, the 75 micron-Al2O3/HDPE composite gave the highest thermal conductivity, which was nearly 50% higher than that of pure HDPE. Enhancement in impact strength and Hardness Rockwell were up to 300% and 400% as compared to the pure HDPE respectively. The Al2O3 with small particle size is generally more efficient for the enhancement of the impact strength.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Enhancement of High-Density Polyethylene Properties by Impregnation with Inorganic Alumina Filler
    AU  - Koyejo Oduola
    AU  - Fabian Ozioko
    Y1  - 2017/04/27
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    N1  - https://doi.org/10.11648/j.ajche.s.2017050301.16
    DO  - 10.11648/j.ajche.s.2017050301.16
    T2  - American Journal of Chemical Engineering
    JF  - American Journal of Chemical Engineering
    JO  - American Journal of Chemical Engineering
    SP  - 49
    EP  - 54
    PB  - Science Publishing Group
    SN  - 2330-8613
    UR  - https://doi.org/10.11648/j.ajche.s.2017050301.16
    AB  - The influence of filler size and content on the mechanical and rheological properties (thermal conductivity, impact strength, hardness and melt flow index (MFI) of Al2O3/high-density polyethylene (HDPE) composites have been studied. Concentration of alumina was varied up to 30% by weight. The composites were prepared using a two-roll mill and then test specimens were prepared by injection molding. Thermal conductivity, hardness, impact strength and melt flow rate of the composites increased with decreased particle sizes and increased particle content with exceptions at certain concentrations due to non-uniform distributions of particles and agglomerates formed by the particles. As an example, the best integrated thermal conductivity was shown by a 75 micron-Al2O3/HDPE composite at 15% wt. alumina content, while the 212 micron- Al2O3/HDPE composite at 20 wt.% alumina content. For the same alumina content of 15% concentration by weight out of the three particle sizes. 75, 212 and 850 microns, the 75 micron-Al2O3/HDPE composite gave the highest thermal conductivity, which was nearly 50% higher than that of pure HDPE. Enhancement in impact strength and Hardness Rockwell were up to 300% and 400% as compared to the pure HDPE respectively. The Al2O3 with small particle size is generally more efficient for the enhancement of the impact strength.
    VL  - 5
    IS  - 3-1
    ER  - 

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Author Information
  • Department of Chemical Engineering, University of Port Harcourt, Port Harcourt, Nigeria

  • Department of Chemical Engineering, University of Port Harcourt, Port Harcourt, Nigeria

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