The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.
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Science Journal of Chemistry (Volume 2, Issue 6-2)
This article belongs to the Special Issue Polyelectrolytes & Dyes |
| DOI | 10.11648/j.sjc.s.2014020602.12 |
| Page(s) | 8-13 |
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Cationic Dye, Metachromasy, Anionicpolyelectrolytes, Electrostatic Interaction, Aggregation
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APA Style
Nandini Ratnakar. (2014). A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Science Journal of Chemistry, 2(6-2), 8-13. https://doi.org/10.11648/j.sjc.s.2014020602.12
ACS Style
Nandini Ratnakar. A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Sci. J. Chem. 2014, 2(6-2), 8-13. doi: 10.11648/j.sjc.s.2014020602.12
AMA Style
Nandini Ratnakar. A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Sci J Chem. 2014;2(6-2):8-13. doi: 10.11648/j.sjc.s.2014020602.12
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Download@article{10.11648/j.sjc.s.2014020602.12,
author = {Nandini Ratnakar},
title = {A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes},
journal = {Science Journal of Chemistry},
volume = {2},
number = {6-2},
pages = {8-13},
doi = {10.11648/j.sjc.s.2014020602.12},
url = {https://doi.org/10.11648/j.sjc.s.2014020602.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.s.2014020602.12},
abstract = {The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.},
year = {2014}
}
TY - JOUR T1 - A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes AU - Nandini Ratnakar Y1 - 2014/09/23 PY - 2014 N1 - https://doi.org/10.11648/j.sjc.s.2014020602.12 DO - 10.11648/j.sjc.s.2014020602.12 T2 - Science Journal of Chemistry JF - Science Journal of Chemistry JO - Science Journal of Chemistry SP - 8 EP - 13 PB - Science Publishing Group SN - 2330-099X UR - https://doi.org/10.11648/j.sjc.s.2014020602.12 AB - The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction. VL - 2 IS - 6-2 ER -
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